Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 534, Issue -, Pages 312-321Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2018.09.037
Keywords
Zinc-trimesic acid; Mesoporous carbon nanofiber; NiCo2O4 nanosheet; O-functionalization; Pseudocapacitance
Categories
Funding
- National Key Research and Development Program of China [2018YFB1105100]
- National Natural Science Foundation of China [51471187]
- Science Foundation of China University of Petroleum, Beijing [24620188JC005]
Ask authors/readers for more resources
Core-shell structured carbon nanofiber@metal oxide is one of the most promising hybrid electrodes as supercapacitors, in which the pseudocapacitive metal oxides can be fully exerted and stabilized on the carbonaceous scaffolds. However, facile fabrication of mesoporous carbon nanofibers and integration of them with metal oxides are challenging. Herein, we report a new type of mesoporous carbon nanofibets (MCNs), derived from zinc-trimesic acid fibers, acting as the scaffolds to anchor nickel cobaltite (NiCo2O4) nanosheets after surface O-functionalization. The resultant core-shell OMCN@NiCo2O4 nanostructure is demonstrated by scanning electron microscope (SEM), elemental mapping, bright-field/highresolution transmission electron microscope (TEM), selected area electron diffraction (SAED) studies. The anchored NiCo2O4 nanosheets are dense (97.4%), and have a strong interaction with OMCN, as revealed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and H2-temperature programmed reduction (H-2-TPR) techniques. As expected, the OMCN@NiCo2O4 is highly efficient, showing a high specific capacitance of 1631 F g(-1) at the current density of 1 A g(-1), excellent rate capability and superior cycling stability up to 5000 cycles within a high capacitance retention ratio of 94.5%. This research opens the avenue to fabricate high-efficiency carbon-metal oxide electrodes using metal-organic framework fiber-derived mesoporous carbon nanofibers and integration of them with NiCo2O4 nanosheets by increasing the interfacial interaction. (C) 2018 Elsevier Inc. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available