Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 149, Issue 20, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.5055593
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Funding
- Swedish Research Council (VR)
- Knut and Alice Wallenberg Foundation, Sweden
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Energy selected and mass-resolved electron-ion coincidence spectra of heavy water have been recorded for ionization energies from 18 to 35 eV. Dissociation from the (BB2)-B-2 state produces both O+ and D-2(+) at energies near their thermodynamic thresholds in addition to the known products D+ and OD+. The relative yields of O+, OD+, and D+ in the (BB2)-B-2 state breakdown diagram are modulated by the vibrational structure of the B-state population, implying incomplete energy equilibration before fragmentation. Decay from the C-state produces OD+ in addition to the known O+ and D+. The fragment kinetic energies suggest that O+ and D+ from the C state are the products of full atomization of the molecule. Published by AIP Publishing.
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