4.7 Article

Communication: Strong-interaction limit of an adiabatic connection in Hartree-Fock theory

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 149, Issue 24, Pages -

Publisher

AIP Publishing
DOI: 10.1063/1.5078565

Keywords

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Funding

  1. European Research Council [648932]
  2. NWO through Rubicon [019.181EN.026]

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We show that the leading term in the strong-interaction limit of the adiabatic connection that has as weak-interaction expansion the Moller-Plesset perturbation theory can be fully determined from a functional of the Hartree-Fock density. We analyze this functional and highlight similarities and differences with the strong-interaction limit of the density-fixed adiabatic connection case of Kohn-Sham density functional theory. Published by AIP Publishing.

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