Preparation and adsorption mechanism of polyvinyl alcohol/graphene oxide-sodium alginate nanocomposite hydrogel with high Pb(II) adsorption capacity

A series of polyvinyl alcohol (PVA)/graphene oxide (GO)-sodium alginate (SA) nanocomposite hydrogel beads were prepared through in situ crosslinking for Pb2+ removal. It was found that PVA and SA molecules were intercalated into GO layers through hydrogen bonding interactions, leading to the destruction of orderly structure of GO, while GO uniformly distributed in PVA matrix. With increasing PVA solution concentration, the hydrogel beads became more regular, a large number of polygonal pores with thin walls and open pores formed, the average pore size decreased, and the dense network structure formed. Meanwhile, the permeability of the composite hydrogel decreased, leading to the decline of Pb2+ adsorption capacity of the composite hydrogel. With increasing GO content, the ballability of the hydrogel beads was weakened, the pore size increased, and relatively loose network structure formed, resulting in an increase in permeability and Pb2+ adsorption capacity of the hydrogel, reaching up to 279.43 mg g(-1). Moreover, the composite hydrogel presented relatively good reusability for Pb2+ removal. The adsorption mechanism was explored and showed that the adsorption system of the composite hydrogel belonged to the second-order kinetic model and fitted Langmuir adsorption isotherm model for Pb2+ removal, which might be mono-layer chemical adsorption. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47318.