4.7 Article

Non-precious co-catalysts boost the performance of TiO2 hierarchical hollow mesoporous spheres in solar fuel cells

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 43, Issue 46, Pages 21219-21230

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2018.10.012

Keywords

Water splitting; Hollow spheres; Co-catalyst; Graphene; Impedance

Funding

  1. American University in Cairo

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A main challenge hindering the development of efficient solar fuel cell systems is the identification of robust, cost-effective, and abundant catalysts. Herein, we demonstrate the ability to synthesize photoactive, relatively cheap and abundant catalyst for the solar-assisted water splitting. The proposed catalyst is a composite of Co-Cu/graphene immobilized on hierarchical hollow mesoporous Titania. Diffuse Reflectance analysis showed visible light absorption for (Co-Cu) (2%)-TiO2/RGO with an estimated band gap of 2.41 eV, as compared to 3.13 eV for Titania. Photoluminescence spectra showed a significant decreasing in recombination rate of photogenerated electron-hole pair for (Co-Cu) (2%)-TiO2/RGO nanocomposites. Upon their use as photoanodes in solar fuel cells, the fabricated nanocomposites show 14-fold increase in photocurrent density compared to Titania. This enhancement was confirmed via the measurement of electron and phonon life times. The results attained in this study demonstrate a step toward using non-precious co-catalysts to boost the performance of photocatalysts in solar fuel cells. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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