4.2 Article

Highly Oxygen-Permeable NiV2O6-25 wt % V2O5 Molten-Oxide Membrane Material

Journal

INORGANIC MATERIALS
Volume 54, Issue 10, Pages 1055-1061

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0020168518100114

Keywords

composites; oxygen; membrane materials; oxide melts; chemical diffusion

Funding

  1. Russian Science Foundation [16-19-10608]
  2. Russian Federation Ministry of Education and Science [007-00129-18-00]
  3. Federal Agency for Scientific Organizations of Russia [007-GZ/Ch3363/26]
  4. Russian Science Foundation [16-19-10608] Funding Source: Russian Science Foundation

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A NiV2O6-25 wt % V2O5 molten-oxide material has been prepared and characterized, and its transport properties (electrical conductivity, oxygen ion transport number, and oxygen permeability) have been studied in the temperature range 680-700A degrees C. The results demonstrate that the molten-oxide membrane material obtained possesses high selective oxygen permeability (KO2 = (2.5-5.6) x 10(-10) mol/(cm s) in the range 680-740A degrees C and j(O2)/j(N2) similar to 1500) and can be used in separators for the preparation of extrapure oxygen from air.

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