Journal
INORGANIC CHEMISTRY
Volume 58, Issue 1, Pages 57-60Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b02856
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Funding
- National Natural Science Foundation of China [21371048]
- Natural Science Foundation of Henan Province [134300510035, 162300410015]
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An organic-inorganic hybridized polyoxotungstate which contains two kinds of covalently linked tungstate clusters in its polyanion has been obtained. The three clusters are connected by glutamic acid molecules and europium atoms through Eu-O-C bonds. The cluster in the middle position is a tetramer. Two of the same clusters at two sides are dimers that are functionalized by glutamic acid molecules. The solid-state luminescence of this compound exhibited the characteristic emission of Eu3+ centers with a lifetime of 232 mu s.
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