Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 57, Issue 44, Pages 14878-14888Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.8b04406
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Funding
- National Natural Science Foundation of China [51672222]
- Doctorate Foundation of Northwestern Polytechnical University [CX201720]
- Spaceflight Innovation Foundation of China
- Spaceflight Foundation of China [2014-HT-XGD]
- Natural Science Basic Research Plan in Shaanxi Province of China [2018JQ5160]
- Fundamental Research Funds for the Central Universities [3102017zy048]
- Analytical & Testing Center of Northwestern Polytechnical University
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To overcome the defects of weak impedance matching and low attenuation of electromagnetic wave absorption materials, we herein report hollow ZnxFe3-xO4@porous MnO2/rGO conductive network composites synthesized by some facile reactions. The special three-in-one structure of hollow, core-shell and porous is sufficiently conducive to the absorption of electromagnetic wave by composites. Compared with binary hollow ZnxFe3-xO4@porous MnO2 and rGO/hollow ZnxFe3-xO4 composites, the ternary composites show the excellent electromagnetic wave absorption performance in both reflection loss and bandwidth. The maximum reflection loss of -50.6 dB occurs at 8.96 GHz and effective bandwidth below -10 dB (90% attenuation of electromagnetic wave) can shift from 3.6 GHz to 18.0 GHz with a thickness of 1.5-5.5 mm. The glorious absorption properties mostly derive from synergistic effect of magnetic and dielectric loss. These results endow rGO/hollow ZnxFe3-xO4@porous MnO2 composites with potential application in various fields of military radar, electronic communication, weaponry and aerospace.
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