Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 6, Pages 1242-1250Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201801610
Keywords
Amines; Oxidation; Azo compounds; Imines; Disulfides
Categories
Funding
- CSIR-India [HCP0008, BSC0108]
- DST-SERB
- CSIR
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A transition metal-free protocol has been developed for the oxidative coupling of primary amines to imines and azobenzenes, thiols to disulfides, and 2-aminothiophenols to benzothiazoles, offering excellent yields. The advantageous features of the present environmentally benign methodology include the usage of biocompatible and green reaction conditions such as, solvent, room temperature reactions and transition metal-free approach. Moreover, it offers a broader substrate scope.
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