Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 1, Pages 104-111Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201801290
Keywords
1,3,5-Triarylbenzene; 4-Aryl-NH-1,2,3-triazole; Cycloaddition; Mesoporous materials; Palladium
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Funding
- funding agency CCOST, Raipur (ENDT) [2096/CCOST/MRP/2017]
- SD NASA-EPSCOR [NNX12AB17G]
- [NSF-CHE-0722632]
- [NSF-CHE-0840507]
- [NSF-EPS-0903804]
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We report mesoporous nano-Pd-MCM-41 catalyzed rapid and efficient synthesis of 1,3,5-triarylbenzenes via de-nitrative cyclotrimerization of beta-nitrostyrenes. All the reactions were very fast and high yielding. The Pd-MCM-41 was also very effective in catalyzing de-nitrative [3+2] cycloaddition of beta-nitrostyrenes with TMSN3 to synthesize 4-aryl-NH-1,2,3-triazoles. The catalyst was reused at least up to eight times with minimum loss of catalytic activity.
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