Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 15, Pages 2124-2133Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201801206
Keywords
Ruthenium; Photocatalysis; Pyrazole ligands; Oxidation; Aqua complexes
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Funding
- Spanish Ministerio de Economia y Competitividad [CTQ2015-66143-P]
- Generalitat de Catalunya [2017-SGR-1720]
- Universitat de Girona [MPCUdG2016/048]
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Different synthetic routes have been developed to obtain the aqua complex trans-[Ru-II(trpy)(pypz-H)(OH2)](PF6)(2), Ru6. This complex, together with the chlorido intermediate complexes cis- and trans-[(RuCl)-Cl-II(pypz-H)(trpy)](+), Ru5a and Ru5b, have been fully characterized by analytical, spectroscopic, and electrochemical methods. Furthermore, the trans-Ru5b complex has been characterized in the solid state through single-crystal X-ray diffraction analysis. The aqua complex Ru6 was tested as catalyst in the photooxidation of alcohols in water and in the chemical oxidation of alkenes, displaying a good performance with high selectivity values in both catalytic processes.
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