Eclogites as palaeodynamic archives: Evidence for warm (not hot) and depleted (but heterogeneous) Archaean ambient mantle

Some high-Mg eclogite xenoliths, entrained by kimberlites from the mantle lithospheres of ancient continental cores, and rare orogenic eclogites and ophiolites, exhumed or obducted during the closure of palaeo-ocean basins, have elemental and isotopic compositions indicative of protoliths that formed as little-differentiated melts erupted in ancient ocean floors. Despite metamorphism and, in part, partial melt loss, these samples of ancient mid-ocean ridge basalt and picrite retain a memory of the chemical and physical state of their protoliths' ambient convecting mantle sources. Published data show that, when filtered to exclude specimens with cumulate protoliths or showing evidence for later enrichment (metasomatism), the samples lack Y or Al2O3 depletion relative to TiO2 and MgO. This indicates melt segregation of the protolith predominantly from a garnet-free peridotite source and implies intersection of the solidus at low pressures (<= 3 GPa). Given the dependence of melt composition and volume on source composition (assumed to be similar to modern depleted mantle) and mantle potential temperature (T-P), we calculate moderate average melt fractions F (similar to 0.22 +/- 0.01) from the Ti contents of the least differentiated samples in three sample suites with 2.6 to 2.9 Ga ages. This converts to T-P of similar to 1410 +/- 10 degrees C assuming a final pressure of melting of 0.5 GPa, melt productivity of 10%/GPa and mantle adiabat of 0.4 degrees C/km, and using a mantle solidus parameterisation. Though model-dependent, the results are in agreement with recent work advocating moderate Archaean mantle T-P. Estimates drop to F = 0.19 and T-P = 1380 degrees C at 1.9 Ga and F = 0.12 and T-P = 1310 at 0.6 Ga, corresponding to a decrease in T-P of only similar to 100 degrees C over the last 3 Ga. A less depleted mantle source yields higher F and T-P, but the above estimates are in better agreement with qualitative evidence from Al2O3 and Y, and with Nd-Hf and Sr isotope compositions of orogenic eclogite and granulite suites and mantle eclogites, respectively, which indicate that portions of the Meso- to Neoarchaean mantle were depleted. Moderate T-P supports early plate strengthening and a possible transition to plate tectonics in the Mesoarchaean if not earlier. Moreover, moderate temperatures in Archaean subduction zones may have facilitated deep recycling of volatiles that would otherwise have been lost from subducting slabs at shallow depths. (C) 2018 Elsevier B.V. All rights reserved.