Journal
CORROSION SCIENCE
Volume 149, Issue -, Pages 185-194Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2019.01.019
Keywords
Corrosion inhibitor; Click reaction; 1,2,3-triazole; Copper catalyzed; Mild steel; Acidic medium
Funding
- Coordenactio de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
- Fundacao de Amparo a Pesquisa do Estado do Rio de Janeiro (FAPERJ) [E-26/102.971/2012, E-26/111.407/2013]
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- Vicerrectoria de Investigacion of the Universidad de Costa Rica [115-B2-A52]
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1-benzyl-4-phenyl-1H-1,2,3-triazole was prepared using an environmental friendly and facile synthetic procedure and its performance as an organic corrosion inhibitor for mild steel in 1.0 mol L-1 HCl was investigated using four different methods. An average efficiency of 81.7% was obtained with 2.13 mmol L-1 solutions of the organic compound. A new approach to classical electrochemical analyses confirms the inhibitor adsorption on the metal surface. Temperature effect studies in the oxidation inhibition behavior as well as calculated thermodynamic parameters are consistent with a chemisorption process and Atomic Force Microscopy shows the formation of a protective film.
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