Journal
COMPTES RENDUS CHIMIE
Volume 21, Issue 12, Pages 1075-1094Publisher
centre Mersenne pour ldition scientifique ouverte
DOI: 10.1016/j.crci.2018.02.011
Keywords
Spin crossover (SCO); Optical spectra; LIESST; Relaxation studies; Ultrafast spectroscopy
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Funding
- Aquitaine Region
- CNRS
- University of Bordeaux
- ANR
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This article overviews the different light-induced spin-crossover processes that are induced using ligand photoreaction, photothermal effects, or optical absorption of the center metallic ion. A particular attention is drawn on the light-induced excited spin-state trapping effect, the most studied phenomenon, by discussing the recent developments in terms of description of the initial photoswitching process and the mechanisms developing at different time scales, as well as the lifetime of the photoinduced state. (C) 2018 Published by Elsevier Masson SAS on behalf of Academie des sciences.
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