Journal
CHINESE JOURNAL OF POLYMER SCIENCE
Volume 37, Issue 3, Pages 243-252Publisher
SPRINGER
DOI: 10.1007/s10118-019-2192-5
Keywords
Ionic liquid; Graphene; PLLA; Crystallization; Dielectric behavior
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Funding
- National Natural Science Foundation of China [51603060]
- Fundamental Research Funds for the Central Universities [JZ2017YYPY0250]
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To investigate the performance of graphene (Gra) modified with ethoxycarbonyl ionic liquid (IL), chain mobility and crystallization kinetics of poly(L-lactic acid) (PLLA), a series of PLLA nanocomposites have been prepared using solution-cast method. IL can improve the dispersion of Gra in PLLA matrix and the samples containing IL have higher growth rate of PLLA spherulite than neat PLLA does. PLLA/IL/Gra and PLLA/2Gra exhibit the same relaxation strength and time of (N) relaxation that corresponds to the longest normal mode motion at 110-140 degrees C. PLLA/IL/Gra shows a faster crystallization rate than PLLA/2Gra does, which might be attributed to the Gra-imidazolium cation interaction in IL modified Gra, the significant dispersion effect of IL at Gra surface, and the increase of nuclei density of PLLA/IL/Gra.
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