Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 36, Issue 12, Pages 1222-1240Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201800427
Keywords
C-H bond activation; iron; imido; nitrene; hydrogen atom abstraction
Categories
Funding
- National Key Research and Development Program [2016YFA0202900]
- National Natural Science Foundation of China [21725104, 21690062, 21432001]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
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Transition-metal-catalyzed C-H bond amination reaction is an attractive method for the synthesis of amines. Fueled by the growing interests in the development of economical and eco-friendly catalysts for organic transformations, there are great recent efforts on developing iron-catalyzed C-H bond amination reactions using organic azides, sulfonyl azides, and iminoiodanes as nitrene source. This review summarizes the progress achieved in the field since 2011. The reaction scope, the synthetic utility of the catalytic reaction, and the current mechanistic understandings of the C-H bond amination reactions catalyzed by hemoproteins, iron porphyrins and phthalocyanines, non-heme-type iron complexes, as well as metal-organic- framework-supported iron complexes are introduced and discussed.
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