4.5 Article

Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates Involving Sequential Olefins Insertion and Borylation Reaction

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 37, Issue 2, Pages 140-147

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201800536

Keywords

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Funding

  1. National Program on Key Research Project [2016YFA0602900]
  2. National Natural Science Foundation of China [21420102003]
  3. Guangdong Province Science Foundation [2017B090903003]

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The Summary of main observation and conclusion An efficient Pd-catalyzed three-component coupling reaction of allyl carboxylates, norbornenes and diboronates is described, which allows efficient assembly of C(sp(3))-C(sp(3)) and C(sp(3))-B bonds in a single process. Moreover, this approach shows advantages of good chemo- and regioselectivity, as well as good substrates suitability.

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