Journal
CHINESE CHEMICAL LETTERS
Volume 30, Issue 3, Pages 801-805Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2018.12.009
Keywords
Metal-organic frameworks; Selective adsorption; Fluorescence sensing; Fe3+ ion; Nitroaromatic compounds
Categories
Funding
- National Natural Science Foundation of China (NSFC) [21771191]
- Shandong Natural Science Fund [ZR2017QB012]
- Applied Basic Research Projects of Qingdao [16-5-1-95-jch]
- Fundamental Research Funds for the Central Universities [16CX05015A, 18CX06003A, YCX2018071]
- Foundation of State Key Laboratory of Structural Chemistry [20160006]
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Three cadmium(II) metal-organic frameworks (MOFs) based on tetracarboxylate ligands, namely [Cd-2(TTTA)(DMF)(3)]center dot 2DMF(1), [Cd-2(TB)(H2O)(4)]center dot 3DMF center dot H2O (2) and [Cd(TEB)(0.5)]center dot 2DMF center dot 4H(2)O (3) have been designed and synthesized. Complex 1 is a 2-dimensional (2D) 3,4-connected network with 3,4L13 topology, complex 2 features a 3-dimensional (3D) 3,4-connected tfa topology with a 2-fold interpenetrating structure and complex 3 has a 3D 4-connected dia topology with a 4-fold interpenetrating structure. Interestingly, 2 exhibits permanent pores and selective adsorption of CO2 over CH4. In addition, 2 shows fluorescence sensing of Fe3+ ion and rapid detection of nitroaromatic compounds (NACs) through fluorescence quenching. (C) 2018 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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