Ni/Co-based metal-organic frameworks as electrode material for high performance supercapacitors

A novel bimetallic Ni/Co-based metal-organic framework (Ni/Co-MOF) was successfully synthesized via a simple solvothermal method, and used as electrode material for high performance supercapacitors. After doping of Co element, the Ni/Co-MOF materials retain the original crystalline topology structure of Ni-3(BTC)(2)center dot 12H(2)O. The as-obtained Ni/Co-MOF demonstrates an excellent specific capacitance of 1067 and 780 Fig at current density of 1 and 10 Ng, respectively, and can also retain 68.4% of the original capacitance after 2500 cycles. These results suggest that bimetallic Ni/Co-based MOFs are promising materials for the next generation supercapacitance, owing to their excellent electrochemical performance. The synthetic procedure can be applied to synthesize other bimetallic MOFs and enhance their conductive property. (C) 2018 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.