Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 13, Issue 23, Pages 3718-3722Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201801145
Keywords
[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine; energetic materials; fused rings; nitration; synthesis
Categories
Funding
- NSFC [21772011]
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Treatment of heterocyclic amines featuring fused rings of [1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine with fuming HNO3/P2O5 leads to six fully characterized explosives through multiple nitration and reduction or oxidation mechanism. Thus, 4-nitro-N-(3-nitro[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-yl)-1,2,5-oxadiazol-3-amine (3 b, TTDNF) showed high performance (D=9180 m s(-1), P=36.7 GPa) and low impact sensitivity (IS>40 J) while N-([1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-yl)-3-nitro-1,2,4-oxadiazol-5-amine (4 a, TTNOA) exhibited a potential cast explosive component with low melting point at 88.2 degrees C and high onset decomposition temperature at 226.2 degrees C.
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