Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 70, Pages 18629-18633Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201804373
Keywords
covalent triazine frameworks; microporous materials; N-heterocyclic carbenes; organocatalysis; porous polymers
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Funding
- Federal Ministry of Education and Research (BMBF) [03XP0030]
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The successful incorporation of a thermally fragile imidazolium moiety into a covalent triazine framework resulted in a heterogeneous organocatalyst active in carbene-catalyzed umpolung reaction. The structural integrity of the imidazolium moiety was confirmed by combining solid-state NMR and XPS experiments.
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