Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 6, Pages 1379-1390Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201804592
Keywords
amine-borane; catalysis; dehydrogenation; dehydropolymerization; polyaminoborane
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Funding
- EPSRC [EP/MO24210/1]
- EPSRC [EP/M024210/1] Funding Source: UKRI
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The dehydropolymerization of amine-boranes, exemplified as H2RBR center dot NR ' H-2, to produce polyaminoboranes (HRBNR ' H)(n) that are inorganic analogues of polyolefins with alternating main-chain B-N units, is an area with significant potential, stemming from both fundamental (mechanism, catalyst development, main-group hetero-cross-coupling) and technological (new polymeric materials) opportunities. This Concept article outlines recent advances in the field, covering catalyst development and performance, current mechanistic models, and alternative non-catalytic routes for polymer production. The substrate scope, polymer properties and applications of these exciting materials are also outlined. Challenges and opportunities in the field are suggested, as a way of providing focus for future investigations.
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