Journal
CHEMISTRY LETTERS
Volume 48, Issue 4, Pages 361-363Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.181018
Keywords
Cross-coupling; Oligothiophene; Silicon
Categories
Funding
- JST, ACT-C [JPMJCR12Z1]
- JSPS [18J12593, 17K19127]
- Grants-in-Aid for Scientific Research [17K19127, 18J12593] Funding Source: KAKEN
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Aryl(triethyl) silanes were found to cross-couple with aryl chlorides by palladium/copper dual catalysis and XPhos as a crucial ligand. The catalyst system is applicable to a facile oligothiophene synthesis from thienyl(trialkyl) silanes and thienyl chlorides. As the starting silanes are readily accessible by the catalytic C-H silylation, our method provides a protocol for a rapid biaryl synthesis starting with aromatic hydrocarbons straightforwardly.
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