Journal
CHEMICAL REVIEWS
Volume 119, Issue 4, Pages 2192-2452Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.8b00507
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Funding
- Alexander von Humboldt Foundation
- European Research Council under the Seventh Framework Program of the European Community (FP7 2007-2013
- ERC) [307535]
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C-H activation has surfaced as an increasingly powerful tool for molecular sciences, with notable applications to material sciences, crop protection, drug discovery, and pharmaceutical industries, among others. Despite major advances, the vast majority of these C-H functionalizations required precious 4d or 5d transition metal catalysts. Given the cost-effective and sustainable nature of earth-abundant first row transition metals, the development of less toxic, inexpensive 3d metal catalysts for C-H activation has gained considerable recent momentum as a significantly more environmentally-benign and economically-attractive alternative. Herein, we provide a comprehensive overview on first row transition metal catalysts for C-H activation until summer 2018.
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