Journal
CHEMICAL PHYSICS LETTERS
Volume 712, Issue -, Pages 149-154Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2018.10.002
Keywords
Pd nanoparticles; Benzyl alcohol oxidation; Carbon layer; 3D TiO2
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In this work, a uniform thickness of a two-dimensional carbon layer wrapping a three-dimensional flower-like TiO2 (CFT) is used to support Pd nanoparticles (Pd/CFT) as efficient catalyst for selective oxidation of benzyl alcohol in a three-phase reaction system. The results of characterization reveal that the Ti-O-C bond plays a key role in establishing interactions between the CFT and Pd. In comparison to the Pd/AC catalyst, Pd nanoparticles (PdNPs) with active phases can be effectively anchored on the surfaces of CFT without obvious dynamic change under reaction conditions.
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