Journal
CATALYSIS COMMUNICATIONS
Volume 118, Issue -, Pages 81-85Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2018.10.001
Keywords
Photoredox-catalyzed; Perfluoroalkylation; Aminoquinolines; Hypervalent iodine(III); Perfluorocarboxylic acid
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Funding
- Shandong Provincial Natural Science Foundation [ZR2017LB006]
- Science Foundation of Educational Commission of Shandong Province of China [J17KA248]
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A practical approach for photoredox-catalyzed perfluoroalkylation of aminoquinolines with C6F5I(OCORDf)(2) has been developed. In this reaction, pentafluoroiodobenzene can be recovered and further utilized for the synthesis of C6F5I(OCORf)(2). Importantly, this strategy provides a practical access for the application of perfluorocarboxylic acid as the perfluoroalkyl source. A radical pathway mechanism is suggested according to the results of control experiments.
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