4.6 Article

Design of Superior Ethanol Gas Sensor Based on Al-Doped NiO Nanorod-Flowers

Journal

ACS SENSORS
Volume 1, Issue 2, Pages 131-136

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssensors.5b00123

Keywords

Al-doped NiO; nanorod-flowers; solvothermal; gas sensor; ethanol

Funding

  1. National Nature Science Foundation of China [61374218, 61134010, 61327804]
  2. Program for Chang Jiang Scholars and Innovative Research Team in University [IRTI3018]
  3. National High-Tech Research and Development Program of China (863 Program) [2013AA030902, 2014AA06A505]
  4. Graduate Innovation Fund of Jilin University [2015094]

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The pure and Al-doped NiO nanorod-flowers with uniform sizes and well-defined morphologies were synthesized for the first time by a facile solvothermal reaction. As the gas sensing materials of MOS gas sensors, their sensing properties were investigated systematically. The results indicated that the 2.15 at% Al-doped NiO nanorod-flowers showed improved gas sensing properties compared to those of pure NiO nanorod-flowers. The incorporation of Al ions with NiO nanocrystals adjusts the carrier concentration, and induces the change of the oxygen deficiency and chemisorbed oxygen of NiO nanorod-flowers. Thus, the doping of Al3+ into NiO nanorod-flowers should be a promising method for designing and fabricating the high performance gas sensor.

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