4.6 Review Book Chapter

Using Noble Gases to Assess the Ocean's Carbon Pumps

Journal

ANNUAL REVIEW OF MARINE SCIENCE, VOL 11
Volume 11, Issue -, Pages 75-103

Publisher

ANNUAL REVIEWS
DOI: 10.1146/annurev-marine-121916-063604

Keywords

ocean carbon cycle; noble gases; solubility pump; ventilation; air-sea exchange; bubbles; biological pump

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Natural mechanisms in the ocean, both physical and biological, concentrate carbon in the deep ocean, resulting in lower atmospheric carbon dioxide. The signals of these carbon pumps overlap to create the observed carbon distribution in the ocean, making the individual impact of each pump difficult to disentangle. Noble gases have the potential to directly quantify the physical carbon solubility pump and to indirectly improve estimates of the biological organic carbon pump. Noble gases are biologically inert, can be precisely measured, and span a range of physical properties. We present dissolved neon, argon, and krypton data spanning the Atlantic, Southern, Pacific, and Arctic Oceans. Comparisons between deep-ocean observations and models of varying complexity enable the rates of processes that control the carbon solubility pump to be quantified and thus provide an important metric for ocean model skill. Noble gases also provide a powerful means of assessing air-sea gas exchange parameterizations.

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