Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 6, Pages 1774-1778Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811004
Keywords
amidyl radical; eosin Y; metal free; photoredox catalysis; unactivated C-H Bonds
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Funding
- University at Albany, State University of New York
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The development of visible-light-mediated allylation of unactivated sp(3) C-H bonds is reported. The remote allylation was directed by the amidyl radical, which was generated by photocatalytic fragmentation of a pre-functionalized amide precursor. Both aromatic and aliphatic amide derivatives could successfully deliver the remote C-H allylation products in good yields. A variety of electron deficient allyl sulfone systems could be used as -carbon radical acceptor.
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