Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 11, Pages 3392-3397Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201813646
Keywords
alkynes; allylation; amines; photoredox; rhodium
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Funding
- Alexander von Humboldt Foundation
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A rhodium/photoredox dual catalyzed regiodivergent alpha-allylation of amines is described. As an atom-economic and efficient method, alkynes and allenes are used as allylic electrophile surrogates in this novel protocol. With different reaction conditions, synthetically useful branched or linear homoallylic amines could be synthesized in good to excellent yields and regioselectivity. This straightforward strategy complements the traditional transition-metal catalyzed allylation reactions.
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