Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 2, Pages 552-556Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811015
Keywords
cloverphenes; nanographenes; polycyclic aromatic hydrocarbons; starphenes; star-shaped nanographenes
Categories
Funding
- Basque Science Foundation for Science (Ikerbasque)
- POLYMAT
- University of the Basque Country [GIU17/054]
- University of the Basque Country (SGIker)
- Gobierno de Espana (Ministerio de Economia y Competitividad) [CTQ2016-77970-R]
- Gobierno Vasco (BERC programme)
- Portuguese Foundation for Science and Technology [IF/00894/2015]
- CICECO-Aveiro Institute of Materials [POCI-01-0145-FEDER-007679]
- CICECO-Aveiro Institute of Materials (FCT) [UID/CTM/50011/2013]
- European Union's Horizon 2020 research and innovation programme [664878]
- European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme [722951]
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Star-shaped nanographenes (SNGs) are large monodisperse polycyclic aromatic hydrocarbons that are larger than a nanometer and have shown a lot of promise in a wide range of applications including electronics, energy conversion, and sensing. Herein, we report a new family of giant star-shaped N-doped nanographenes with diameters up to 6.5 nm. Furthermore, the high solubility of this SNG family in neutral organic solvents at room temperature allowed a complete structural, optoelectronic, and electrochemical characterisation, which together with charge transport studies illustrate their n-type semiconducting character.
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