Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 2, Pages 592-595Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811782
Keywords
allyl complexes; boron; homogeneous catalysis; palladium
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Funding
- NIH [GM-R35-127140]
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Organoboron ate complexes undergo a net vinyl insertion reaction to give 1,1-disubstituted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst. Reactions that employ vinyllithium afforded good to excellent yields after one hour, while reactions that employ vinylmagnesium chloride furnished modest to good yields after 18 hours.
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