Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 6, Pages 1749-1753Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201813191
Keywords
aluminum-free; asymmetric catalysis; C-H activation; nickel; SPOs
Categories
Funding
- DFG [SPP 1807]
- DFG (Gottfried Wilhelm Leibniz award)
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Highly enantioselective nickel-catalyzed alkene endo-hydroarylations were accomplished with full selectivity by organometallic C-H activation. The asymmetric assembly of chiral six-membered scaffolds proved viable in the absence of pyrophoric organoaluminum reagents within an unprecedented nickel/JoSPOphos manifold.
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