Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 34, Pages 11586-11598Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201813523
Keywords
excited-state Pd complex; palladium; photochemistry; radical reactions
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Palladium catalysis induced by visible light is an emerging field of catalysis. In contrast to classical reactions catalyzed by Pd complexes in the ground state, which mostly proceed through two-electron redox processes, the mechanisms of these new methods based on photoexcited Pd complexes usually operate through transfer of a single electron. Such processes lead to putative hybrid Pd/radical species, which exhibit both radical and classical Pd-type reactivity. This Minireview highlights the recent progress in this rapidly growing area.
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