Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 14, Pages 4592-4595Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201814488
Keywords
C-H alkylation; electrochemistry; oxidation; photoelectrochemistry; radical reactions
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Funding
- MOST [2016YFA0204100]
- NSFC [21672178]
- Fundamental Research Funds for the Central Universities
- National Postdoctoral Program for Innovative Talents [BX201700141]
- China Postdoctoral Science Foundation [2018M630730]
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A photoelectrochemical method for the C-H alkylation of heteroarenes with organotrifluoroborates has been developed. The merger of electrocatalysis and photoredox catalysis provides a chemical oxidant-free approach for the generation and functionalization of alkyl radicals from organotrifluoroborates. A variety of heteroarenes were functionalized using primary, secondary, and tertiary alkyltrifluoroborates with excellent regio- and chemoselectivity.
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