Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 6, Pages 1719-1723Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201812533
Keywords
carboboration; copper; cross-coupling; homogeneous catalysis; palladium
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Funding
- Indiana University
- NIH [R01GM114443]
- Vice Provost for Research through the Research Equipment Fund
- NSF [CHE1726633]
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Two methods are reported for the 1,2- and 1,1-arylboration of -methyl vinyl arenes. In the case of 1,2-arylboration, the formation of a quaternary center occurred through a rare cross-coupling reaction of a tertiary organometallic complex. 1,1-Arylboration was enabled by catalyst optimization and occurred through a -hydride elimination/reinsertion cascade. Enantioselective variants of both processes are presented as well as mechanistic investigations.
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