Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 5, Pages 1407-1411Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811894
Keywords
carbon dioxide; glycerol; polyacrylates; polycarbonates; pressure-sensitive adhesives
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Funding
- NSF [CHE-0619339]
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Insertion of CO2 into the polyacrylate backbone, forming poly(carbonate) analogues, provides an environmentally friendly and biocompatible alternative. The synthesis of five poly(carbonate) analogues of poly(methyl acrylate), poly(ethyl acrylate), and poly(butyl acrylate) is described. The polymers are prepared using the salen cobalt(III) complex catalyzed copolymerization of CO2 and a derivatized oxirane. All the carbonate analogues possess higher glass-transition temperatures (T-g = 32 to -5 degrees C) than alkyl acrylates (T-g = 10 to -50 degrees C), however, the carbonate analogues (T-d approximate to 230 degrees C) undergo thermal decomposition at lower temperatures than their acrylate counterparts (T-d approximate to 380 degrees C). The poly(alkyl carbonates) exhibit compositional-dependent adhesivity. The poly(carbonate) analogues degrade into glycerol, alcohol, and CO2 in a time-and pH-dependent manner with the rate of degradation accelerated at higher pH conditions, in contrast to poly(acrylate)s.
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