In Situ Analysis of Surface Catalytic Reactions Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy

Electrochemistry and heterogeneous catalysis continue to attract enormous interest. In situ surface analysis is a dynamic research field capable of elucidating the catalytic mechanisms of reaction processes. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) is a non-destructive technique that has been cumulatively used to probe and analyze catalytic-reaction processes, providing important spectral evidence about reaction intermediates produced on catalyst surfaces. In this perspective, we review recent electrochemical- and heterogeneous-catalysis studies using SHINERS, highlight its advantages, summarize the flaws and prospects for improving the SHINERS technique, and give insight into its future research directions.