Journal
ANALYTICA CHIMICA ACTA
Volume 1054, Issue -, Pages 38-46Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2018.12.028
Keywords
Microcystins; MSPE; Magnetic gamma-cyclodextrin polymer; HPLC-MS/MS
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Funding
- National Nature Sciences Foundation of China [21575028, 21605022]
- Program for Changjiang Scholar and Innovative Research Team in University [IRT15R11]
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Microcystins (MCs), which are produced by eruptive cyanobacteria, seriously threaten the health of humans for their poisonousness. Herein, a facile strategy was introduced to synthesize the magnetic gamma-cyclodextrin polymer (Fe3O4@PDA@gamma-CDP) composite and set it as a novel adsorbent with excellent properties for the magnetic solid-phase extraction (MSPE) of MCs. The prepared Fe3O4@PDA@gamma-CDP microspheres exhibit good aqueous dispersibility and highly affinity for MCs, thus contribute to an excellent extraction performance for trace MCs in water samples. Combined with HPLC-MS/MS, a handy, sensitive and efficient method was developed for detection of MCs in water samples, which shows good linearity (R-2 >= 0.9992) in the range of 1.0-1000 pg mL(-1), low limits of detection (0.8-2.0 pg mL(-1), S/N = 3), satisfactory repeatability with the relative standard deviations (RSDs) lower than 6.2% (n = 5). At last, the proposed method was successfully applied for the extraction and detection of MCs in fresh water and sea water samples, which provides great potential of trace-level MCs determination in lake and sea water. (C) 2018 Elsevier B.V. All rights reserved.
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