Micropatterning Silver Nanowire Networks on Cellulose Nanopaper for Transparent Paper Electronics

Transparent microelectrodes with high bend-ability are necessary to develop lightweight, small electronic devices that are highly portable. Here, we report a reliable fabrication method for transparent and highly bendable microelectrodes based on conductive silver nanowires (AgNWs) and 2,2,6,6-tetramethylpiperidine-l-oxy (TEMPO)-oxidized cellulose nanofibers (CNFs). The AgNW-based micropatterns were simply fabricated on glass via poly(ethylene glycol) photolithography and then completely transferred to transparent TEMPO-CNF nanopaper with high bendability via vacuum-assisted microcontact printing (mu CP). The AgNW micropatterns were embedded in the surface layer of TEMPO-CNF nanopaper, enabling strong adhesion to the nanopaper substrate. The resulting AgNW micropatterns on the TEMPO-CNF nanopaper showed an optical transparency of 82% at 550 nm and a sheet resistance of 54 Omega/sq when the surface density of AgNWs was as low as 12.9 mu g/cm(2). They exhibited good adhesion stability and excellent bending durability. After 12 peeling test cycles and 60 s sonication time, the sheet resistance of the AgNW networks embedded on TEMPO-CNF nanopaper increased by only similar to 0.12 and similar to 0.07 times, respectively. Furthermore, no significant change in electrical resistance was observed even after 3 bending cycles to nearly 90 degrees and 500 cycles of 80% bending strain. Moreover, the AgNW patterns on TEMPO-CNF paper were successfully applied for constructing a transparent electric circuit as well as a solid-state electrochromic device. Overall, we proposed an effective way to fabricate AgNW micropatterns on transparent nanopaper, which can be expanded to various conductive materials for high-performance paper-based electronics.