4.8 Article

Dual-Function Electrochromic Supercapacitors Displaying Real-Time Capacity in Color

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 50, Pages 43993-43999

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b15066

Keywords

electrochromism; supercapacitors; multifunctional electronics; electrochemical devices; ion gels

Funding

  1. National Research Foundation of Korea (NRF) - Korea government (MSIT) [NRF-2016R1C1B2006296]
  2. Human Resources Program in the Transportation Specialized Lighting Core Technology Development from the Ministry of Trade, Industry & Energy, Republic of Korea [N0001364]
  3. Korea Evaluation Institute of Industrial Technology (KEIT) [N0001364] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  4. National Research Foundation of Korea [2016R1C1B2006296] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Dual-function electrochromic supercapacitors (ECSs) that indicate their real-time charge capacity in color are fabricated using tungsten trioxide (WO3) and Li-doped ion gels containing hydroquinone (HQ). The ECSs can simultaneously serve as either electrochromic devices or supercapacitors. The coloration/bleaching and charging/discharging characteristics are investigated between 0 and -1.5 V. At the optimal HQ concentration, large transmittance contrast (similar to 91%), high coloration efficiency (similar to 61.9 cm(2)/C), high areal capacitance (similar to 13.6 mF/cm(2)), and good charging/discharging cyclic stability are achieved. Flexible ECSs are fabricated on plastic substrates by exploiting the elastic characteristics of the gel electrolytes, and they exhibit good bending durability. Moreover, practical feasibility is evaluated by demonstrating the use of the ECSs as an energy storage device and a power source.

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