Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 45, Pages 39222-39227Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b14480
Keywords
light illumination; trap states; blue-shift emission; surface collapse; photodegradation mechanism
Funding
- Independent Research Fund Denmark-Sapere Aude starting grant [7026-00037A]
- Swedish Research Council VR starting grant [2017-05337]
- European Commission's Erasums+ Program
- China Scholarship Council
- Swedish Energy Agency (STEM) [44651-1]
- European Union [GINOP-2.3.6-15-2015-00001]
- European Regional Development Fund
- Helmholtz recognition award
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All-inorganic CsPbI3 perovskite quantum dots (QDs) have attracted intense attention for their successful application in photovoltaics (PVs) and optoelectronics that are enabled by their superior absorption capability and great photoluminescence (PL) properties. However, their photostability remains a practical bottleneck and further optimization is highly desirable. Here, we studied the photostability of as-obtained colloidal CsPbI3 QDs suspended in hexane. We found that light illumination does induce photodegradation of CsPbI3 QDs. Steady-state spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and transient absorption spectroscopy verified that light illumination leads to detachment of the capping agent, collapse of the CsPbI3 QD surface, and finally aggregation of surface Pb-0. Both dangling bonds containing surface and Pb-0 serve as trap states causing PL quenching with a dramatic decrease of PL quantum yield. Our work provides a detailed insight about the correlation between the structural and photophysical consequences of the photo-degradation process in CsPbI3 QDs and may lead to the optimization of such QDs toward device applications.
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