Supramolecular Design of Donor-Acceptor Complexes via Heteroatom Replacement toward Structure and Electrical Transporting Property Tailoring

A feasible strategy relies on using heteroatom replacement, namely, chemical modification of an organic compound. Here we present this design concept for donor acceptor complexes, which involves introducing nitrogen atoms to the middle ring of donor molecules to promote short contacts and reduce steric effect of the mixed framework. These nitrogen -modified complexes can possess a shorter molecular distance besides the mixed -stacking pathway, enlarged r x interactions, or even a scarce 1:2.5 molar ratio through extra acceptor insertion. As a result, the unique 1:2 complex with nitrogen atoms on the different sides demonstrated stable electron field-effect mobility performance, whereas the binary system with no nitrogen replacement or N atoms on the identical sides displayed poor ambipolar properties. These results confirmed that heteroatom replacement was a powerful molecular design tool to fine-tune the molecular packing of organic donor acceptor complexes and their corresponding electronic properties.