Journal
SCIENCE CHINA-MATERIALS
Volume 62, Issue 3, Pages 437-447Publisher
SCIENCE PRESS
DOI: 10.1007/s40843-018-9318-7
Keywords
polyurethane network; disulfide bond; self-healing; shape-memory
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Funding
- National Natural Science Foundation of China [51773131, 51721091]
- International S&T Cooperation Project of Sichuan Province [2017HH0034]
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With the prompt development in intellectualization nowadays, the smart materials with multi-functionality or multi-responsiveness are highly expected. But it is a big challenge to integrate the different actuating units into a single system in a synergy pattern. Herein, we put forward a new strategy to develop the polyurethane networks which can present shape-memory effect and self-healing effect in independent way as well as simultaneous acting mode. To realize this goal, poly(tetremethylene ether) glycol was chosen as the soft segment to ensure the polymer chains a good mobility, and disulfide bond as the dynamic covalent bond was embedded in the backbone of polyurethane to endow it with desirable self-healing capacity under mild condition. Moreover, a rational control of the architecture of the networks by adjusting the content of disulfide bond and the degree of cross-linking, a broad glass transition temperature (T-g) was achieved, which enabled the network a versatile shape-memory effect, covering from dual-, triple- so far as to quadruple-shape memory effect. More importantly, the shape recovery and healing process can be realized simultaneously because of the highly matched actuating condition in this system.
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