Journal
MATERIALS RESEARCH LETTERS
Volume 2, Issue 4, Pages 233-240Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/21663831.2014.932858
Keywords
MAX Phase; Solid Solution; Rietveld Analysis; HRTEM; Lattice Parameter
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Funding
- National Science Foundation [DMR 1310245]
- Department of Energy's Office of Nuclear Energy University Program [CFP-11-3231]
- SSF synergy grant FUNCASE Functional Carbides and Advanced Surface Engineering
- Knut and Alice Wallenberg Foundation
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We synthesized the following previously unreported aluminum-containing solid solution M(n+1)AX(n) phases: (Ti-0.5, V-0.5)(3)AlC2, (Nb-0.5, V-0.5)(2)AlC, (Nb-0.5, V-0.5)(4)AlC3 and (Nb-0.8, Zr-0.2)(2)AlC. Rietveld analysis of powder X-ray diffraction patterns was used to calculate the lattice parameters and phase fractions. Heating Ti, V, Al and C elemental powders-in the molar ratio of 1.5: 1.5: 1.3: 2-to 1, 450 degrees C for 2 h in flowing argon, resulted in a predominantly phase pure sample of (Ti-0.5, V-0.5)(3)AlC2. The other compositions were not as phase pure and further work on optimizing the processing parameters needs to be carried out if phase purity is desired.
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