Journal
ACS CENTRAL SCIENCE
Volume 1, Issue 8, Pages 456-462Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscentsci.5b00332
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Funding
- NIGMS NIH HHS [R01 GM106210] Funding Source: Medline
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1205646] Funding Source: National Science Foundation
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Kinetic, spectroscopic, and computational studies of radical C-H arylations highlight the interplay between chemical and physical rate processes in these multiphase reactions. Anomalous concentration dependences observed here may be reconciled by considering the role of phase transfer processes that mediate concentrations in each phase. In addition, understanding interactions through phase boundaries enables their use in optimization of reaction performance.
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