Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 1, Issue 7, Pages 777-781Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00143e
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Funding
- National Science Foundation of China [21202167]
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A Cu-mediated direct conversion of aromatic C-H to C-NH2 assisted by a chelating group was developed. The reaction employed TMSN3 as a nitrogen source under redox-neutral conditions to provide a variety of N-heterocycle-substituted primary anilines. Neither external oxidant nor additional deprotection or reduction step was required in this process.
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