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Catalytic asymmetric allylation of carbonyl compounds and imines with allylic boronates

Journal

ORGANIC CHEMISTRY FRONTIERS
Volume 1, Issue 3, Pages 303-320

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3qo00081h

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Funding

  1. National Natural Science Foundation of China [21290184, 21172236]
  2. National Basic Research Program of China [2010CB833200]
  3. Chinese Academy of Sciences

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Enantioselective allylation is a highly used organic reaction to prepare chiral homoallylic alcohols and amines, which serve as important building blocks in the synthesis of a variety of natural products and pharmaceuticals. In particular, catalytic asymmetric allylation of carbonyl compounds and imines with organoboronates has seen rapid development in the past decade and is the focus of this review.

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