Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 1, Issue 7, Pages 738-741Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00135d
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Funding
- National Natural Science Foundation of China [21325209]
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A novel type of open-chain chiral chelating olefin bearing a simple monophosphite unit with a binaphthyl backbone was designed and synthesized, which could serve as an elegant chiral bidentate ligand in the rhodium-catalyzed asymmetric 1,2-additions of organoboron reagents to alpha-diketones and N-sulfonyl aldimines.
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