Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 1, Issue 4, Pages 365-367Publisher
CHINESE CHEMICAL SOC
DOI: 10.1039/c4qo00027g
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- Singapore National Research Foundation [NRF-RF2008-10]
- Nanyang Technological University
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A new biarylmonophosphine was developed for highly asymmetric arylation and vinylation of silyl enolates of acyclic esters with good generality. The new stereocenters alpha to the ester groups were formed in high enantiomeric excess. The method was applied to the asymmetric synthesis of Profen drugs on a gram scale.
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